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master's thesis
Toplinska svojstva kompozita polilaktidna kiselina/modificirane koštice masline
diplomski rad
2020. urn:nbn:hr:167:088456
Folo, Franka
University of Split
Faculty of Chemistry and Technology
Division of Engineering and Chemistry

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Folo, F. (2020). Toplinska svojstva kompozita polilaktidna kiselina/modificirane koštice masline : diplomski rad (Master's thesis). Split: University of Split, Faculty of Chemistry and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:167:088456

Folo, Franka. "Toplinska svojstva kompozita polilaktidna kiselina/modificirane koštice masline : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:167:088456

Folo, Franka. "Toplinska svojstva kompozita polilaktidna kiselina/modificirane koštice masline : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:167:088456

Folo, F. (2020). 'Toplinska svojstva kompozita polilaktidna kiselina/modificirane koštice masline : diplomski rad', Master's thesis, University of Split, Faculty of Chemistry and Technology, accessed 02 January 2025, https://urn.nsk.hr/urn:nbn:hr:167:088456

Folo F. Toplinska svojstva kompozita polilaktidna kiselina/modificirane koštice masline : diplomski rad [Master's thesis]. Split: University of Split, Faculty of Chemistry and Technology; 2020 [cited 2025 January 02] Available at: https://urn.nsk.hr/urn:nbn:hr:167:088456

F. Folo, "Toplinska svojstva kompozita polilaktidna kiselina/modificirane koštice masline : diplomski rad", Master's thesis, University of Split, Faculty of Chemistry and Technology, Split, 2020. Available at: https://urn.nsk.hr/urn:nbn:hr:167:088456

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Metadata
TitleToplinska svojstva kompozita polilaktidna kiselina/modificirane koštice masline : diplomski rad
Title (english)Thermal properties of poly(lactic acid)/modified olive stone flour composites : diploma thesis
AuthorFranka Folo
MentorSanja Perinović Jozić (mentor)
Committee memberLadislav Vrsalović (predsjednik povjerenstva)
Committee memberMiroslav Labor (član povjerenstva)
Committee memberSanja Perinović Jozić (član povjerenstva)
GranterUniversity of Split
Faculty of Chemistry and Technology
(Division of Engineering and Chemistry)
Split
Defense date and country2020-11-27, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Abstract
Modifikacija svojstava polilaktidne kiseline (PLA) provedena je dodatkom modificiranih mljevenih koštica masline (mMKM) s ciljem priprave biorazgradljivog kompozita. Uspješno su pripravljeni polimerni kompoziti svih sastava pomoći na ekstruderu s rotirajućim cilindrom. Diferencijalna pretražna kalorimetrija (DSC) je primijenjena u istraživanju utjecaja različitih udjela mMKM na toplinska svojstva i kristalnost PLA. Toplinska svojstva i kristalnost PLA u kompozitima PLA/mMKM ukazuju na slabe interakcije izmeĎu punila i kompozita. Punilo mMKM u kompozitima PLA/mMKM ima samo ulogu zamjene dijela skupljeg materijala s jeftinijim. Toplinska postojanost kompozita istraživana je primjenom neizotermne termogravimetrije (TG). Kompoziti PLA/mMKM se razgraĎuju do tri stupnja razgradnje. mMKM pogoršava toplinsku postojanost polimernih kompozita. Buduća istraživanja treba usmjeriti k promijeni modifikatora ili postupka modifikacije površine MKM kako bi se uspostavile jače interakcije izmeĎu punila i polimerne matrice čime bi se dobila bolja svojstva polimernog materijala.
Abstract (english)
The modification of the properties of poly(lactid acid) (PLA) was performed by adding modified olive stone flour (mMKM) with the aim of preparing a biodegradable composite. Polymer composites of all compositions have been successfully prepared using a rotary cylinder extruder. Influence of different proportions of mMKM on the thermal properties and crystallinity was investigated using differential screening calorimetry (DSC). The thermal properties and crystallinity of PLA in PLA/mMKM composites indicate weak interactions between fillers and composites. The mMKM filler in PLA/mMKM composites has just the role of replacing a part of the more expensive material with a cheaper one. The thermal stability of the composite was investigated using non-isothermal thermogravimetry (TG). PLA/mMKM composites are degraded in three degradation stages. mMKM degrades the thermal stability of polymer composites. Future research should focus on changing the MKM surface modifier or surface modification process to establish stronger interactions between the filler and the polymer matrix to obtain better properties of the polymeric material
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:167:088456
Study programmeTitle: Chemical Technology; specializations in: Materials, Environmental Protection, Mediteranean Cultures, Materials and Environmental protection
Course: Materials
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra inženjer/inženjerka kemijskog inženjerstva (magistar/magistra inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2021-01-12 07:14:25