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master's thesis
Priprava membrane LaF3 postupkom taloženja La3+ i F- uz dodatak Eu(NO3)3 za FISE
diplomski rad
2018. urn:nbn:hr:167:636769
Grbelja, Iva
University of Split
Faculty of Chemistry and Technology
Division of Chemistry

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Grbelja, I. (2018). Priprava membrane LaF3 postupkom taloženja La3+ i F- uz dodatak Eu(NO3)3 za FISE : diplomski rad (Master's thesis). Split: University of Split, Faculty of Chemistry and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:167:636769

Grbelja, Iva. "Priprava membrane LaF3 postupkom taloženja La3+ i F- uz dodatak Eu(NO3)3 za FISE : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2018. https://urn.nsk.hr/urn:nbn:hr:167:636769

Grbelja, Iva. "Priprava membrane LaF3 postupkom taloženja La3+ i F- uz dodatak Eu(NO3)3 za FISE : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2018. https://urn.nsk.hr/urn:nbn:hr:167:636769

Grbelja, I. (2018). 'Priprava membrane LaF3 postupkom taloženja La3+ i F- uz dodatak Eu(NO3)3 za FISE : diplomski rad', Master's thesis, University of Split, Faculty of Chemistry and Technology, accessed 20 November 2024, https://urn.nsk.hr/urn:nbn:hr:167:636769

Grbelja I. Priprava membrane LaF3 postupkom taloženja La3+ i F- uz dodatak Eu(NO3)3 za FISE : diplomski rad [Master's thesis]. Split: University of Split, Faculty of Chemistry and Technology; 2018 [cited 2024 November 20] Available at: https://urn.nsk.hr/urn:nbn:hr:167:636769

I. Grbelja, "Priprava membrane LaF3 postupkom taloženja La3+ i F- uz dodatak Eu(NO3)3 za FISE : diplomski rad", Master's thesis, University of Split, Faculty of Chemistry and Technology, Split, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:167:636769

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Metadata
TitlePriprava membrane LaF3 postupkom taloženja La3+ i F- uz dodatak Eu(NO3)3 za FISE : diplomski rad
Title (english)Preparation LaF3 membrane by precipitation of La3+ and F- with additiom Eu(NO3)3 for FISE : diploma thesis
AuthorIva Grbelja
MentorMarija Bralić (mentor)
MBZ: 119816
Committee memberAnte Prkić (predsjednik povjerenstva)
Committee memberJosipa Giljanović (član povjerenstva)
Committee memberMarija Bralić (član povjerenstva)
GranterUniversity of Split
Faculty of Chemistry and Technology
(Division of Chemistry)
Split
Defense date and country2018-10-23, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Cilj rada je dobivanje slabo topljivog taloga LaF 3 taloženjem NaF s La(NO 3 ) 3 uz dodatak europija. Talog je dobiven taloženjem uz miješanje, bez miješanja te uz povremeno miješanje. Membrane su pripravljene miješanjem dobivenog taloga s europijem. Pripravljen membrane su se umetale u laboratorijski izrađeno tijelo za elektrodu. Odzivne karakteristike elektrode ispitivane su metodom slijednog razrjeđenja počevši od koncentracije fluorida 10 -1 do 10 -7 mol L -1 . Unutarnji elektrolitni kontakt postignut je korištenjem otopine KCl, c( KCl) = 3 mol L -1 . S ciljem postizanja boljih odzivnih karakteristike na površinu membrana nanosile su se nanočestice Fe X O Y . Pripravljene membrane pokazale su linearnu promjenu potencijala u koncentracijskom području od 10 -1 do 10 -2 mol L -1 s promjenom potencijala po koncentracijskoj dekadi od 10,00 do 24,29 mV. Najbolje odzivne karakteristike pokazala je nekondicionirana membrana dobivena prešanjem 0,45 g LaF 3 i 0,05 g teflona s 3% europija.
Abstract (english)
The aim of this diploma thesis is gaining low soluble precipitate of LaF 3 from NaF and La(NO 3 ) 3 with addition of Europium. Precipitate is obtained by percipitating with stirring, without stirring and periodically stirring. Membranes are prepared by mixing gained precipitate with Europium. The prepared membranes were inserted into a body made in laboratory for electrodes with purpose of measuring potential of the electrode. The response characteristic for the electrode were tested by sequential dilution starting with the fluoride concentration from 10 -1 to 10 -7 mol L -1 . Interior electrolyte contact was achieved using solution KCl, c(KCl) = 3 mol L -1 . To get better response characteristics Fe X O Y nanoparticles were to be applied to the surface of the membrane. Prepared membranes showed linear change of potential in concentration area of 10 -1 to 10 -2 mol L -1 along with potential change at concentration decade of 10,00 to 24,29 mV. Unconditioned membrane, made with pressing of 0,45 g LaF 3 and 0,05 g teflone with 3% Europium, showed the best responsive characteristics.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:167:636769
Study programmeTitle: Chemistry; specializations in: Environmental Protection, Organic Chemistry and Biochemistry
Course: Environmental Protection
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Public noteKljučne riječi doradio knjižničar/ Key words are revised by the librarian
Created on2019-06-28 09:44:33