Priprava ionskog senzora na bazi paste od grafita za određivanje acebutolola uz tetrafenilborat i fosfomolibdat kao anionski dio IAC-a

Škutin, Lana

prikaz prve stranice dokumenta Priprava ionskog senzora na bazi paste od grafita za određivanje acebutolola uz tetrafenilborat i fosfomolibdat kao anionski dio IAC-a

master's thesis

Priprava ionskog senzora na bazi paste od grafita za određivanje acebutolola uz tetrafenilborat i fosfomolibdat kao anionski dio IAC-a

diplomski rad

2022. urn:nbn:hr:167:066729

Škutin, Lana

University of Split
Faculty of Chemistry and Technology
Division of Chemistry

Cite this document

APA 6th Edition

Škutin, L. (2022). Priprava ionskog senzora na bazi paste od grafita za određivanje acebutolola uz tetrafenilborat i fosfomolibdat kao anionski dio IAC-a : diplomski rad (Master's thesis). Split: University of Split, Faculty of Chemistry and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:167:066729

MLA 8th Edition

Škutin, Lana. "Priprava ionskog senzora na bazi paste od grafita za određivanje acebutolola uz tetrafenilborat i fosfomolibdat kao anionski dio IAC-a : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2022. https://urn.nsk.hr/urn:nbn:hr:167:066729

Chicago 17th Edition

Harvard

Škutin, L. (2022). 'Priprava ionskog senzora na bazi paste od grafita za određivanje acebutolola uz tetrafenilborat i fosfomolibdat kao anionski dio IAC-a : diplomski rad', Master's thesis, University of Split, Faculty of Chemistry and Technology, accessed 23 April 2024, https://urn.nsk.hr/urn:nbn:hr:167:066729

Vancouver

Škutin L. Priprava ionskog senzora na bazi paste od grafita za određivanje acebutolola uz tetrafenilborat i fosfomolibdat kao anionski dio IAC-a : diplomski rad [Master's thesis]. Split: University of Split, Faculty of Chemistry and Technology; 2022 [cited 2024 April 23] Available at: https://urn.nsk.hr/urn:nbn:hr:167:066729

IEEE

L. Škutin, "Priprava ionskog senzora na bazi paste od grafita za određivanje acebutolola uz tetrafenilborat i fosfomolibdat kao anionski dio IAC-a : diplomski rad", Master's thesis, University of Split, Faculty of Chemistry and Technology, Split, 2022. Available at: https://urn.nsk.hr/urn:nbn:hr:167:066729

Cite this item: https://urn.nsk.hr/urn:nbn:hr:167:066729

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Title	Priprava ionskog senzora na bazi paste od grafita za određivanje acebutolola uz tetrafenilborat i fosfomolibdat kao anionski dio IAC-a : diplomski rad
Title (english)	Prepatation of ion sensor based on graphite paste for determination of acebutolol with tetraphenlyborate and phosphomolybdate as anionic part of IAC : diploma thesis
Author	Lana Škutin
Mentor	Marija Bralić (mentor)
Committee member	Ante Prkić (predsjednik povjerenstva)
Committee member	Josipa Giljanović (član povjerenstva)
Committee member	Marija Bralić (član povjerenstva)
Granter	University of Split Faculty of Chemistry and Technology (Division of Chemistry) Split
Defense date and country	2022-07-14, Croatia
Scientific / art field, discipline and subdiscipline	NATURAL SCIENCES Chemistry
Abstract	Elektrode na bazi paste od ugljika (CPE) su posebne heterogene ugljikove elektrode koje čini smjesa ugljikovih pasti pripravljenih s različitim udjelima grafita, veziva, ionsko-asocijacijskog kompleksa, soli. CPE imaju široku primjenu u određivanju elektrokemijski aktivnih spojeva. U ovom radu pripravljen je potenciometrijski senzor na bazi paste od grafita uz PMA i TPB kao anionskog dijela IAC-a za određivanje acebutolola u realnim uzorcima. Pripravljene su i testirane 22 paste s različitim udjelima grafita, tekućih veziva (TEPh, DEHA, NPOE) i IAC-a (ACBTPB, ACBPMA) pri pH vrijednosti 5. U paste s najboljim odzivnim karakteristikama dodana je mala količina soli NaTPB-a. Najbolje odzivne karakteristike pokazala je pasta 16 pripravljena od 54,8% grafita, 44,8% TEPh-a, 0,3% IAC-a ACB PMA i 0,1% NaTPB. Promjena potencijala po koncentracijskoj dekadi je u rasponu od -36,3 mV do -51,8 mV. Elektroda je drugi dan mjerenja nakon prvog poliranja pokazala najbolju promjenu potencijala po koncentracijskoj dekadi od -51,0 mV odnosno -51,8 mV u području linearnosti od 3,16×10 -6 M do 3,16×10 -3 M. Vrijeme uspostave stabilnog odziva je 60 s.
Abstract (english)	Carbon paste electrodes are special group of heterogeneous carbon electrodes mixture of carbon pastes are prepared with different parts of grahite, binder, ion-association complex and salt. CPE are widely used as working electrodes for the determination of electrochemically active compounds. In this experiment are prepared the potentiometric sensor based on graphite paste with tetraphenylborate and phosphomolybdate as anionic part of ionic-association complex for determination of acebutolol in real samples. 22 pastes with different proportions of graphite, liquid binders (TEPh, DEHA, NPOE) and IAC (ACBTPB, ACBPMA) were prepared and tested at pH 5. A small amount of NaTPB salt was added to the pastes with the best response characteristics. The best response characteristics were shown by paste 16 prepared from 54.8% graphite, 44.8% TEPh, 0.3% IAC ACB PMA and 0.1% NaTPB. The change in potential per concentration decade ranges from -36.3 mV to -51.8 mV. On the 2 nd day of measurement after the 1 st polish, the electrode showed the best potential change per concentration decade from -51.0 mV and -51.8 mV in the linearity range from 3.16×10 -6 M to 3.16×10 -3 M. The time to establish a stable response is 60 s.
Keywords
Keywords (english)
Language	croatian
URN:NBN	urn:nbn:hr:167:066729
Study programme	Title: Chemistry; specializations in: Environmental Protection, Organic Chemistry and Biochemistry Course: Environmental Protection Study programme type: university Study level: graduate Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resource	Text
File origin	Born digital
Access conditions	Open access Embargo expiration date: 2022-08-21
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Created on	2022-07-21 07:59:01