prikaz prve stranice dokumenta Voltametrijsko određivanje nikla u tlu elektrodom od staklastog ugljika modificiranog slojem žive
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master's thesis
Voltametrijsko određivanje nikla u tlu elektrodom od staklastog ugljika modificiranog slojem žive
diplomski rad
2018. urn:nbn:hr:167:352337
Đaković, Ana
University of Split
Faculty of Chemistry and Technology
Division of Chemistry

Cite this document

Đaković, A. (2018). Voltametrijsko određivanje nikla u tlu elektrodom od staklastog ugljika modificiranog slojem žive : diplomski rad (Master's thesis). Split: University of Split, Faculty of Chemistry and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:167:352337

Đaković, Ana. "Voltametrijsko određivanje nikla u tlu elektrodom od staklastog ugljika modificiranog slojem žive : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2018. https://urn.nsk.hr/urn:nbn:hr:167:352337

Đaković, Ana. "Voltametrijsko određivanje nikla u tlu elektrodom od staklastog ugljika modificiranog slojem žive : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2018. https://urn.nsk.hr/urn:nbn:hr:167:352337

Đaković, A. (2018). 'Voltametrijsko određivanje nikla u tlu elektrodom od staklastog ugljika modificiranog slojem žive : diplomski rad', Master's thesis, University of Split, Faculty of Chemistry and Technology, accessed 08 December 2024, https://urn.nsk.hr/urn:nbn:hr:167:352337

Đaković A. Voltametrijsko određivanje nikla u tlu elektrodom od staklastog ugljika modificiranog slojem žive : diplomski rad [Master's thesis]. Split: University of Split, Faculty of Chemistry and Technology; 2018 [cited 2024 December 08] Available at: https://urn.nsk.hr/urn:nbn:hr:167:352337

A. Đaković, "Voltametrijsko određivanje nikla u tlu elektrodom od staklastog ugljika modificiranog slojem žive : diplomski rad", Master's thesis, University of Split, Faculty of Chemistry and Technology, Split, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:167:352337

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Metadata
TitleVoltametrijsko određivanje nikla u tlu elektrodom od staklastog ugljika modificiranog slojem žive : diplomski rad
Title (english)Voltametric determination of nickel in soil by mercury-film modified glassy carbon electrode : diploma thesis
AuthorAna Đaković
MentorMaša Buljac (mentor)
MBZ: 325126
Committee memberMarijo Buzuk (predsjednik povjerenstva)
Committee memberIvica Blažević (član povjerenstva)
Committee memberMaša Buljac (član povjerenstva)
GranterUniversity of Split
Faculty of Chemistry and Technology
(Division of Chemistry)
Split
Defense date and country2018-10-26, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U ovom radu je ispitivana koncentracija nikla u uzorcima tla voltametrijskom metodom na elektrodi od staklastog ugljika modificiranom slojem žive. Analizirana su tri uzorka tla: komercijalno dostupni organski mineralni supstrat (COMPO SANA® ) i dva uzorka tla uzeta u Botaničkom vrtu Prirodoslovno- matematičkog fakulteta Sveučilišta u Splitu. Za određivanje nikla primijenjena je metoda katodne adsorpcijske voltametrije s pravokutnim izmjeničnim signalom pobude (SWAdCSV), pri čemu se koristio sloj žive na elektrodi od staklastog ugljika. Ova metoda uključuje kompleksaciju nikla s dimetilglioksimom i adsorpciju nastalog kompleksa na sloju žive. Koncentracije nikla u uzorcima izračunate su korištenjem metode standardnog dodatka. Koncentracija nikla u tlu iz botaničkog vrta (c(Ni 2+ ) Tlo1 = 106,97 mg/kg; c(Ni 2+ ) Tlo2 = 179,11 mg/kg) odgovara rasponu koncentracija pronađenom u literaturi (c(Ni 2+ )= 5 - 500 mg/kg), te je viša od koncentracije u organskom mineralnom supstratu (c(Ni 2+ ) Tlo3 = 61,45 mg/kg). Koncentracija u uzorku Tla 3 je viša od navedene na deklaraciji (c(Ni 2+ )= 6,7 mg/kg).
Abstract (english)
In this paper concentracions of nickel in soil samples were determined by voltammetric method on mercury-film modified glassy carbon electrode. Three soil samples were analyzed: commercially available organic mineral substrate (COMPO SANA®) and two samples of soil taken from the Botanical Garden of the Faculty of Science, University of Split. For the determination of nickel, a method of Square-wave Adsorptive Cathodic Stripping Voltammetry (SWAdCSV) was used, using a mercury-film modified glassy carbon electrode. This method includes nickel complexation with dimethylglyoxime and adsorption of that complex on mercury film. The nickel concentrations in the samples were calculated using the standard addition method. The nickel concentracions in soil samples taken from Botanical Garden (c(Ni 2+ ) Soil1 = 106,97 mg/kg; c(Ni 2+ ) Soil2 = 179,11 mg/kg) corresponded to the concentracion range found in literature (c(Ni 2+ )= 5 - 500 mg/kg) and were higher than the concentracion in organic mineral substrate (c(Ni 2+ ) Soil3 = 61,45 mg/kg). Concentration in the sample of Soil 3 was higher than stated on the declaration (c(Ni 2+ )= 6,7 mg/kg).
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:167:352337
ProjectNumber: 1316
Title: Biljke kao izvor bioaktivnih sumporovih spojeva te njihova sposobnost hiperakumulacije metala
Acronym: BioSMe
Leader: Ivica Blažević
Jurisdiction: Croatia
Funder: HRZZ
Study programmeTitle: Chemistry; specializations in: Environmental Protection, Organic Chemistry and Biochemistry
Course: Environmental Protection
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Public noteKljučne riječi doradio knjižničar/ Key words are revised by the librarian
Created on2019-02-11 10:49:53