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undergraduate thesis
Sorpcija Hg(II) na sumporom-impregniranom prirodnom zeolitu klinoptilolitu - određivanje mehanizma sorpcije
završni rad
2022. urn:nbn:hr:167:539769
Čorba, Marija
University of Split
Faculty of Chemistry and Technology
Division of Engineering and Chemistry

Cite this document

Čorba, M. (2022). Sorpcija Hg(II) na sumporom-impregniranom prirodnom zeolitu klinoptilolitu - određivanje mehanizma sorpcije : završni rad (Undergraduate thesis). Split: University of Split, Faculty of Chemistry and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:167:539769

Čorba, Marija. "Sorpcija Hg(II) na sumporom-impregniranom prirodnom zeolitu klinoptilolitu - određivanje mehanizma sorpcije : završni rad." Undergraduate thesis, University of Split, Faculty of Chemistry and Technology, 2022. https://urn.nsk.hr/urn:nbn:hr:167:539769

Čorba, Marija. "Sorpcija Hg(II) na sumporom-impregniranom prirodnom zeolitu klinoptilolitu - određivanje mehanizma sorpcije : završni rad." Undergraduate thesis, University of Split, Faculty of Chemistry and Technology, 2022. https://urn.nsk.hr/urn:nbn:hr:167:539769

Čorba, M. (2022). 'Sorpcija Hg(II) na sumporom-impregniranom prirodnom zeolitu klinoptilolitu - određivanje mehanizma sorpcije : završni rad', Undergraduate thesis, University of Split, Faculty of Chemistry and Technology, accessed 16 November 2024, https://urn.nsk.hr/urn:nbn:hr:167:539769

Čorba M. Sorpcija Hg(II) na sumporom-impregniranom prirodnom zeolitu klinoptilolitu - određivanje mehanizma sorpcije : završni rad [Undergraduate thesis]. Split: University of Split, Faculty of Chemistry and Technology; 2022 [cited 2024 November 16] Available at: https://urn.nsk.hr/urn:nbn:hr:167:539769

M. Čorba, "Sorpcija Hg(II) na sumporom-impregniranom prirodnom zeolitu klinoptilolitu - određivanje mehanizma sorpcije : završni rad", Undergraduate thesis, University of Split, Faculty of Chemistry and Technology, Split, 2022. Available at: https://urn.nsk.hr/urn:nbn:hr:167:539769

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TitleSorpcija Hg(II) na sumporom-impregniranom prirodnom zeolitu klinoptilolitu - određivanje mehanizma sorpcije : završni rad
Title (english)Hg(II) sorption on sulfur-impregnated natural zeolite clinoptilolite - determination of sorption mechanism : bachelor thesis
AuthorMarija Čorba
MentorMarin Ugrina (mentor)
Committee memberMarina Trgo (predsjednik povjerenstva)
Committee memberMaša Buljac (član povjerenstva)
Committee memberMarin Ugrina (član povjerenstva)
GranterUniversity of Split
Faculty of Chemistry and Technology
(Division of Engineering and Chemistry)
Split
Defense date and country2022-09-09, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Abstract
Prirodni zeolit klinoptilolit je kemijski modificiran s otopinom Na 2 S pri 150 °C. Ispitana su sorpcijska svojstva polaznog uzorka, prirodnog zeolita klinoptilolita te dobivenog sumporom- impregniranog prirodnog zeolita prema ionima Hg(II) pri unaprijed definiranim optimalnim uvjetima, pH o =2 i omjeru kruto/tekuće 10 g/L. Maksimalni dobiveni kapacitet sorpcije sumporom-impregniranog prirodnog zeolita prema Hg(II) iznosi 1,02 mmol/g što je za 3,6 puta više u usporedbi s prirodnim zeolitom (0,28 mmol/g). Sorpcijski mehanizam Hg(II) na sumporom-impregniranom prirodnom zeolitu uključuje elektrostatsko privlačenje, ionsku izmjenu i površinsko kompleksiranje uz koprecipitaciju Hg(II) u obliku HgS što je potvrđeno određivanjem količine izmjenjivih zeolitnih kationa kao i SEM- EDS i TG-DTG analizom živom zasićenog sumporom-impregniranog prirodnog zeolita.
Abstract (english)
Natural zeolite clinoptilolite is chemically modified with Na 2 S solution at 150 °C. The sorption properties of the initial sample, natural zeolite clinoptilolite and the obtained sulphur- impregnated natural zeolite towards Hg(II) ions were tested under pre-defined optimal conditions, pH o =2 and a solid/liquid ratio of 10 g/L. The maximum obtained sorption capacity of sulphur-impregnated natural zeolite towards Hg(II) was 1.02 mmol/g, which is 3.6 times more compared to natural zeolite (0.28 mmol/g). The sorption mechanism of Hg(II) on sulphur-impregnated natural zeolite includes electrostatic attraction, ion exchange and surface complexation with coprecipitation of Hg(II) in the form of HgS, which was confirmed by determining the amount of exchangeable zeolite cations as well as SEM-EDS and TG-DTG analysis of mercury saturated sulphur-impregnated natural zeolite.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:167:539769
Study programmeTitle: Chemical Technology; specializations in: Chemical Engineering, Environmental Protection
Course: Chemical Engineering
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
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Created on2022-10-21 06:03:25