Sinteza spojeva s 3-fenil-3-hidroksipropanskom podjedinicom sa svojstvima tekućih kristala

Čulina, Marija

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master's thesis

Sinteza spojeva s 3-fenil-3-hidroksipropanskom podjedinicom sa svojstvima tekućih kristala

diplomski rad

2021. urn:nbn:hr:167:687986

Čulina, Marija

University of Split
Faculty of Chemistry and Technology
Division of Chemistry

Cite this document

APA 6th Edition

Čulina, M. (2021). Sinteza spojeva s 3-fenil-3-hidroksipropanskom podjedinicom sa svojstvima tekućih kristala : diplomski rad (Master's thesis). Split: University of Split, Faculty of Chemistry and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:167:687986

MLA 8th Edition

Čulina, Marija. "Sinteza spojeva s 3-fenil-3-hidroksipropanskom podjedinicom sa svojstvima tekućih kristala : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2021. https://urn.nsk.hr/urn:nbn:hr:167:687986

Chicago 17th Edition

Harvard

Čulina, M. (2021). 'Sinteza spojeva s 3-fenil-3-hidroksipropanskom podjedinicom sa svojstvima tekućih kristala : diplomski rad', Master's thesis, University of Split, Faculty of Chemistry and Technology, accessed 21 November 2024, https://urn.nsk.hr/urn:nbn:hr:167:687986

Vancouver

Čulina M. Sinteza spojeva s 3-fenil-3-hidroksipropanskom podjedinicom sa svojstvima tekućih kristala : diplomski rad [Master's thesis]. Split: University of Split, Faculty of Chemistry and Technology; 2021 [cited 2024 November 21] Available at: https://urn.nsk.hr/urn:nbn:hr:167:687986

IEEE

M. Čulina, "Sinteza spojeva s 3-fenil-3-hidroksipropanskom podjedinicom sa svojstvima tekućih kristala : diplomski rad", Master's thesis, University of Split, Faculty of Chemistry and Technology, Split, 2021. Available at: https://urn.nsk.hr/urn:nbn:hr:167:687986

Cite this item: https://urn.nsk.hr/urn:nbn:hr:167:687986

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Title	Sinteza spojeva s 3-fenil-3-hidroksipropanskom podjedinicom sa svojstvima tekućih kristala : diplomski rad
Title (english)	Synthesis of compounds containing 3-phenyl-3-hydroxypropanoic subunit with liquid crystal properties : diploma thesis
Author	Marija Čulina
Mentor	Franko Burčul (mentor)
Committee member	Ivica Blažević (predsjednik povjerenstva)
Committee member	Mario Nikola Mužek (član povjerenstva)
Committee member	Franko Burčul (član povjerenstva)
Granter	University of Split Faculty of Chemistry and Technology (Division of Chemistry) Split
Defense date and country	2021-09-21, Croatia
Scientific / art field, discipline and subdiscipline	NATURAL SCIENCES Chemistry
Abstract	Pripravljeni su homolozi nesimetriĉnih dimera kako bi se ispitala njihova mezogena svojstva. Dimeri posjeduju 3-fenil-3-hidroksipropansku podjedinicu povezanu esterskom vezom preko neparne alkilne razmaknice s cijanobifenilnom podjedinicom. Pripravljeni dimeri se razlikuju po duljini terminalnih lanaca. Kljuĉna reakcija u sintezi je Reformatskyjeva reakcija kojom je pripravljen etil-3-(4-(benziloksi)fenil)-3- hidroksipropanoat (2) na kojeg je u slijedećim koracima esterskom vezom vezan 4'-(3-hidroksipropil)-[1,1'- bifenil]-4-karbonitril (1). Spoj 1 pripravljen je Suzuki-Miyaura reakcijom. Uz pomoć polarizacijskog optiĉkog mikroskopa i diferencijalne pretražne kalorimetrije ispitana su mezogena svojstva ciljnih molekula. Oba spoja pokazuju svojstva tekućih kristala. Temeljem optiĉke teksture utvrĊeno je da se spojevi samoorganiziraju u antiklinalnu smektiĉku C fazu (SmC A ).
Abstract (english)	H omologues of asymmetric dimers were prepared to examine their mesogenic properties. The dimers possess a 3-phenyl-3-hydroxypropane subunit which is linked to the cyanobiphenyl subunit by an ester bond via an odd alkyl spacer. The prepared dimers differ in the length of the terminal chains. The key reaction in the synthesis is the Reformatsky reaction to prepare ethyl-3-(4-(benzyloxy)phenyl) -3-hydroxypropanoate (2) to which 4'-(3-hydroxypropyl)-[1,1'-biphenyl]-4-carbonitrile (1) is attached in the following steps by an ester bond. Compound 1 was prepared by Suzuki-Miyaura reaction. The mesogenic properties of the target molecules were examined with the help of a polarizing optical microscope and differential scanning calorimetry. Both compounds show the properties of liquid crystals. Based on the optical texture, the compounds were found to self-organize into the anticline smectic C phase (SmCA).
Keywords
Keywords (english)
Language	croatian
URN:NBN	urn:nbn:hr:167:687986
Study programme	Title: Chemistry; specializations in: Environmental Protection, Organic Chemistry and Biochemistry Course: Environmental Protection Study programme type: university Study level: graduate Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resource	Text
File origin	Born digital
Access conditions	Open access
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Created on	2022-01-14 10:22:09