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undergraduate thesis
Primjena prirodnog zeolita u obradi eluata dobivenog ispiranjem živom onečišćenog tla
završni rad
2017. urn:nbn:hr:167:100525
Miličević, Blaženka
University of Split
Faculty of Chemistry and Technology
Division of Engineering and Chemistry

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Miličević, B. (2017). Primjena prirodnog zeolita u obradi eluata dobivenog ispiranjem živom onečišćenog tla : završni rad (Undergraduate thesis). Split: University of Split, Faculty of Chemistry and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:167:100525

Miličević, Blaženka. "Primjena prirodnog zeolita u obradi eluata dobivenog ispiranjem živom onečišćenog tla : završni rad." Undergraduate thesis, University of Split, Faculty of Chemistry and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:167:100525

Miličević, Blaženka. "Primjena prirodnog zeolita u obradi eluata dobivenog ispiranjem živom onečišćenog tla : završni rad." Undergraduate thesis, University of Split, Faculty of Chemistry and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:167:100525

Miličević, B. (2017). 'Primjena prirodnog zeolita u obradi eluata dobivenog ispiranjem živom onečišćenog tla : završni rad', Undergraduate thesis, University of Split, Faculty of Chemistry and Technology, accessed 19 September 2024, https://urn.nsk.hr/urn:nbn:hr:167:100525

Miličević B. Primjena prirodnog zeolita u obradi eluata dobivenog ispiranjem živom onečišćenog tla : završni rad [Undergraduate thesis]. Split: University of Split, Faculty of Chemistry and Technology; 2017 [cited 2024 September 19] Available at: https://urn.nsk.hr/urn:nbn:hr:167:100525

B. Miličević, "Primjena prirodnog zeolita u obradi eluata dobivenog ispiranjem živom onečišćenog tla : završni rad", Undergraduate thesis, University of Split, Faculty of Chemistry and Technology, Split, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:167:100525

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TitlePrimjena prirodnog zeolita u obradi eluata dobivenog ispiranjem živom onečišćenog tla : završni rad
Title (english)Application of natural zeolite in treatment of leachate obtained from mercury contaminated soil : bachelor thesis
AuthorBlaženka Miličević
MentorIvona Nuić (mentor)
Committee memberMarina Trgo (predsjednik povjerenstva)
Committee memberIvana Smoljko (član povjerenstva)
Committee memberIvona Nuić (član povjerenstva)
GranterUniversity of Split
Faculty of Chemistry and Technology
(Division of Engineering and Chemistry)
Split
Defense date and country2017-06-14, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Abstract
Rudnik Idrija u Sloveniji bio je značajan antropogeni izvor žive. Iako je još 1995. godine proizvodnja u rudniku prestala, zbog neučinkovitog pečenja rude tlo u okolici Idrije je vrlo onečišćeno živom čija koncentracija doseže i do 10 000 mg Hg/kg. U tako krškom području živa se površinskim i oborinskim vodama može isprati u dublje slojeve tla te može doći do podzemnih voda. Budući da je živa jedan od najtoksičnijih metala, nužno je pronaći učinkovitu, a isplativu metodu za uklanjanje žive iz onečišćenih voda. U ovome radu ispitana je učinkovitost prirodnog zeolita klinoptilolita veličine čestica 0,6 - 0,8 mm u obradi eluata dobivenog ispiranjem živom onečišćenog tla s područja Idrije. Najveći učinak uklanjanja dobiven je u eluatima s najnižom koncentracijom ukupne žive, koja se smanjila do ispod maksimalno dopuštenih koncentracija. Najveća ravnotežna količina vezane ukupne žive po jedinici mase zeolita postignuta je u eluatima s najvećom koncentracijom ukupne žive te opada smanjenjem početne koncentracije. Prirodni zeolit klinoptilolit može se uspješno primjeniti u obradi voda onečišćenih živom, posebice u slučaju niskih početnih koncentracija ukupne žive. Međutim, u svrhu povećanja učinkovitosti prirodnog zeolita za uklanjanje ukupne žive nužno je poboljšati njegova površinska svojstva za adsorpciju različitih ionskih i organskih vrsta, što se najčešće postiže modifikacijom organskim surfaktantima.
Abstract (english)
The Idrija mine in Slovenia was a significant anthropogenic source of mercury. Although the production in the mine stopped in 1995, the soil in surrounding of Idrija is highly polluted with mercury due to the inefficient ore roasting, so the concentration reaches even up to 10 000 mg Hg/kg. In such karst area, surface and rain waters can leach mercury from contaminated soil to deeper soil layers and then into groundwater. Since mercury is one of the most toxic metals, it is necessary to find an efficient, cost- effective method for its removal from contaminated waters. This paper investigated the efficiency of the natural zeolite clinoptilolite of particle size 0.6 - 0.8 mm in the treatment of the leachate obtained by leaching the mercury contaminated soil of Idrija district. The highest removal efficiency has been obtained in leachates with the lowest concentration of total mercury, which has been decreased to below the maximum permissible concentration. The highest equilibrium quantity of removed total mercury per unit of the zeolite mass has been achieved in the leachates with the highest concentration of total mercury, and decreased by decreasing in initial concentration. The natural zeolite clinoptilolite can be successfully applied for the treatment of mercury contaminated waters, especially in the case of low initial total mercury concentrations. However, in order to increase the efficiency of natural zeolite for total mercury removal, it is necessary to improve the surface properties of zeolite for adsorption of various ionic and organic species, which is most commonly achieved by modification with organic surfactants.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:167:100525
Study programmeTitle: Chemical Technology; specializations in: Chemical Engineering, Environmental Protection
Course: Chemical Engineering
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Public note1. Ovaj rad izveden je u okviru bilateralnog znanstveno-istraživačkog hrvatsko-slovenskog projekta „Primjena prirodnog zeolita za remedijaciju živom onečišćenog tla“ koji financira Ministarstvo znanosti i obrazovanja Republike Hrvatske / This paper was produced within bilateral Croatian-Slovenian scientific research project „Application of Natural Zeolite for Remediation of Mercury Contaminated Soil“ financed by the Ministry of Science and Education of the Republic of Croatia. 2. Ključne riječi doradio knjižničar/ Key words are revised by the librarian.
Created on2018-04-12 12:04:51