prikaz prve stranice dokumenta Koordinacijski spojevi kobalta (II): sinteza, spektroskopska i elektrokemijska istraživanja
  Download
PDF 2.52 MB
master's thesis
Koordinacijski spojevi kobalta (II): sinteza, spektroskopska i elektrokemijska istraživanja
diplomski rad
2022. urn:nbn:hr:167:525493
Pranjić, Jozo
University of Split
Faculty of Chemistry and Technology
Division of Chemistry

Cite this document

Pranjić, J. (2022). Koordinacijski spojevi kobalta (II): sinteza, spektroskopska i elektrokemijska istraživanja : diplomski rad (Master's thesis). Split: University of Split, Faculty of Chemistry and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:167:525493

Pranjić, Jozo. "Koordinacijski spojevi kobalta (II): sinteza, spektroskopska i elektrokemijska istraživanja : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2022. https://urn.nsk.hr/urn:nbn:hr:167:525493

Pranjić, Jozo. "Koordinacijski spojevi kobalta (II): sinteza, spektroskopska i elektrokemijska istraživanja : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2022. https://urn.nsk.hr/urn:nbn:hr:167:525493

Pranjić, J. (2022). 'Koordinacijski spojevi kobalta (II): sinteza, spektroskopska i elektrokemijska istraživanja : diplomski rad', Master's thesis, University of Split, Faculty of Chemistry and Technology, accessed 25 November 2024, https://urn.nsk.hr/urn:nbn:hr:167:525493

Pranjić J. Koordinacijski spojevi kobalta (II): sinteza, spektroskopska i elektrokemijska istraživanja : diplomski rad [Master's thesis]. Split: University of Split, Faculty of Chemistry and Technology; 2022 [cited 2024 November 25] Available at: https://urn.nsk.hr/urn:nbn:hr:167:525493

J. Pranjić, "Koordinacijski spojevi kobalta (II): sinteza, spektroskopska i elektrokemijska istraživanja : diplomski rad", Master's thesis, University of Split, Faculty of Chemistry and Technology, Split, 2022. Available at: https://urn.nsk.hr/urn:nbn:hr:167:525493

Please login to the repository to save this object to your list.
Metadata
TitleKoordinacijski spojevi kobalta (II): sinteza, spektroskopska i elektrokemijska istraživanja : diplomski rad
Title (english)Coordination compounds of cobalt (II): synthesis, spectroscopic and electrochemical research : diploma thesis
AuthorJozo Pranjić
MentorIvana Škugor Rončević (mentor)
Committee memberMarijo Buzuk (predsjednik povjerenstva)
Committee memberBoris-Marko Kukovec (član povjerenstva)
Committee memberIvana Škugor Rončević (član povjerenstva)
GranterUniversity of Split
Faculty of Chemistry and Technology
(Division of Chemistry)
Split
Defense date and country2022-12-20, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Pripravljeni su koordinacijski polimeri kobaltovog(II) iona s miješanim ligandima: derivatima nikotinske kiseline (2-bromnikotinska kiselina ili 2-klornikotinska kiselina) te 1,2-bis(4-piridil)etanom ili 1,2-bis(4- piridil)etenom. Kao metalna sol korišten je kobaltov(II) nitrat heksahidrat, a kao otapala korišteni su DMF i voda. Spojevi su karakterizirani IR spektroskopijom, UV-Vis-NIR spektroskopijom termogravimetrijskom analizom (TGA), diferencijalnom skenirajućom kalorimetrijom (DSC) te cikličkom voltametrijom. Dobiveni su koordinacijski polimeri molekulskih formula: [Co(2-Cl-nic) 2 (1,2-bpeten)] n , [Co(2-Br-nic) 2 (1,2-bpeten)] n , [Co(2- Cl-nic) 2 (1,2-bpetan)] n. Kobaltov(II) ion oktaedarski je koordiniran s četiri O donirajuća liganda (karboksilatni kisici derivata nikotinske kiseline i/ili vode) i s dva piridinska dušikova atoma. Molekule 1,2-bis(4-piridil)etana i 1,2-bis(4-piridil)etena premošćuju kobaltove(II) ione dajući beskonačni jednodimenzijski polimerni lanac.
Abstract (english)
Coordination polymers of cobalt(II) ion with mixed ligands: nicotinic acid derivatives (2- bromonicotinic acid or 2-chloronicotinic acid) and 1,2-bis(4-pyridyl)ethane or 1,2-bis(4-pyridyl)ethene were prepared. Cobalt(II) nitrate hexahydrate was used as the metal salt, and DMF and water were used as the solvent. The compounds were characterized by IR spectroscopy, UV-Vis-NIR spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and cyclic voltammetry. Coordination polymers of molecular formulae were obtained: [Co(2-Cl-nic) 2 (1,2-bpetene)]n, [Co(2-Br-nic) 2 (1,2-bpetene)] n , [Co(2-Cl-nic) 2 (1,2- butane)] n . The cobalt(II) ion is octahedrally coordinated with four donating O ligand (carboxylate oxygens of nicotinic acid derivatives and/or water and with two pyridine nitrogen atoms. Molecules of 1,2-bis(4-pyridyl)ethane and 1,2- bis(4-pyridyl)ethene bridge cobalt(II) ions to give an infinite one-dimensional polymer chain.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:167:525493
Study programmeTitle: Chemistry; specializations in: Environmental Protection, Organic Chemistry and Biochemistry
Course: Environmental Protection
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2023-04-04 07:24:27