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master's thesis
Usporedba potenciometrijskih i spektrometrijskih rezultata određivanja željezovih (III) kationa
diplomski rad
2021. urn:nbn:hr:167:309822
Novosel, Barbara
University of Split
Faculty of Chemistry and Technology
Division of Chemistry

Cite this document

Novosel, B. (2021). Usporedba potenciometrijskih i spektrometrijskih rezultata određivanja željezovih (III) kationa : diplomski rad (Master's thesis). Split: University of Split, Faculty of Chemistry and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:167:309822

Novosel, Barbara. "Usporedba potenciometrijskih i spektrometrijskih rezultata određivanja željezovih (III) kationa : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2021. https://urn.nsk.hr/urn:nbn:hr:167:309822

Novosel, Barbara. "Usporedba potenciometrijskih i spektrometrijskih rezultata određivanja željezovih (III) kationa : diplomski rad." Master's thesis, University of Split, Faculty of Chemistry and Technology, 2021. https://urn.nsk.hr/urn:nbn:hr:167:309822

Novosel, B. (2021). 'Usporedba potenciometrijskih i spektrometrijskih rezultata određivanja željezovih (III) kationa : diplomski rad', Master's thesis, University of Split, Faculty of Chemistry and Technology, accessed 09 December 2024, https://urn.nsk.hr/urn:nbn:hr:167:309822

Novosel B. Usporedba potenciometrijskih i spektrometrijskih rezultata određivanja željezovih (III) kationa : diplomski rad [Master's thesis]. Split: University of Split, Faculty of Chemistry and Technology; 2021 [cited 2024 December 09] Available at: https://urn.nsk.hr/urn:nbn:hr:167:309822

B. Novosel, "Usporedba potenciometrijskih i spektrometrijskih rezultata određivanja željezovih (III) kationa : diplomski rad", Master's thesis, University of Split, Faculty of Chemistry and Technology, Split, 2021. Available at: https://urn.nsk.hr/urn:nbn:hr:167:309822

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Metadata
TitleUsporedba potenciometrijskih i spektrometrijskih rezultata određivanja željezovih (III) kationa : diplomski rad
Title (english)Comparison of potentiometric and spectropfotometric results of determination of iron (II) cation : diploma thesis
AuthorBarbara Novosel
MentorAnte Prkić (mentor)
Committee memberJosipa Giljanović (predsjednik povjerenstva)
Committee memberVesna Sokol (član povjerenstva)
Committee memberAnte Prkić (član povjerenstva)
GranterUniversity of Split
Faculty of Chemistry and Technology
(Division of Chemistry)
Split
Defense date and country2021-07-09, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U ovom radu je ispitan odziv ionsko-selektivne membrane na bazi željezovog(III) fosfata na željezove(III) katione pri pH = 1. Vršilo se testiranje membrane koja je napravljena od željezovog(III) fosfata, srebrovog sulfida, Ag 2 S te politetrafluoretilena (PTFE) koji služi kao neaktivni nosač. Očitanjem potencijala je napravljen grafički prikaz ovisnosti elektrodnog potencijala membrane o aktivitetu željezovih(III) kationa. Usporedbom eksperimentalnih podataka i izračunatih vrijednosti može se utvrditi pokazuje li membrana odziv na željezove(III) katione. Pripravom otopina R 1 – R 5 (Fe 3+ - sulfosalicilna kiselina) te očitanjem apsorbancije na spektrofotometru napravljena je kalibracijska krivulja. Nakon mjerenja promjene apsorbancije s promjenom koncentracije željezovih(III) kationa, metoda UV-Vis apsorpcijske spektrofotometrije se može usporediti s potenciometrijskom metodom. Usporedba se radila tako da se ista koncentracija željezovih(III) kationa određivala i potenciometrijski i spektrofotometrijski. Značajke koje su uzete u obzir kod usporedbe metoda su jednadžbe pravaca te linearna dinamička područja.
Abstract (english)
In this thesis, was tested the response of ion-selective membrane based on iron(III) phosphate to iron(III) cations at pH=1. Tested membrane was made of iron (III) phosphate, silver sulfide, Ag 2 S and polytetrafluoroethylene (PTFE). Polytetraflouroethylene is used as an inactive carrier. Graphical representation of the electrode potential on the activity of iron(III) cations was made. By comparing experimental data and calculated values, it can be determined whether the membrane shows a response to iron(III) cations. A calibration curve was made by preparing solutions R 1 – R 5 (Fe 3+ - sulfosalicylic acid) and reading the absorbance on a spectrophotometer. After measuring the change in absorbance with the change in the concentration of iron(III) cations, the UV-Vis absorption spectrophotometry can be compared with the potentiometric method. The same concentration of iron(III) cations was determined both potentiometrically and spectrophotometrically and then a comparison was made. The compared features were te direction equation and linear dynamic range.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:167:309822
ProjectNumber: UIP-2017-05-6282
Title: Razvoj novih membrana za ionsko-selektivne elektrode s dodatkom nanočestica metala i metalnih oksida
Acronym: NANOISEM
Leader: Ante Prkić
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: UIP
Study programmeTitle: Chemistry; specializations in: Environmental Protection, Organic Chemistry and Biochemistry
Course: Environmental Protection
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2022-02-11 07:14:50